LONDON--Commodities titan Glencore Xstrata PLC (XTA.LN) said Wednesday it has appointed John Mack, the former chief executive and chairman of Morgan Stanley, to its board and said the search for a new chairman is still ongoing.

Mr. Mack will be joined by Peter Grauer as independent non-executive directors and Peter Coates as an executive director.

The combined company, which was formed last month by merging Glencore and Xstrata, is still searching for a new chairman after shareholders ousted John Bond last month. Former BP PLC (BP) CEO Tony Hayward was appointed as interim chairman and is leading the search for a new chairman in consultation with external shareholders.

Mr. Mack is currently a senior advisor to Morgan Stanley. He retired as chairman of the bank in 2011 where he previously served as CEO between June 2005 and December 2009. Before Morgan Stanley, he served as CEO of Credit Suisse Group (CS) and CEO of Credit Suisse First Boston.

Mr. Grauer is chairman of Bloomberg Inc, the global financial media company that was founded in 1981 and where he served as CEO and chairman between 2002 and 2011. Prior to Bloomberg, he served as managing director of Donaldson, Lufkin & Jenrette from 1992 to 2000 when DLJ was acquired by Credit Suisse First Boston, the bank where Mr. Mack was also CEO. He served as managing director and senior partner of CSFB Private Equity until 2002. Mr. Grauer is also director of New York listed DaVita HealthCare Partners Inc. (DVA).

Mr. Coates is currently a senior executive of Glencore Xstrata. Between the Glencore's initial public offering in 2011 and the completion of the merger with Xstrata, Mr. Coates was a Non-Executive Director at Glencore. He was previously Chief Executive of Xstrata's coal business, having joined the company in 2002 when Glencore sold its Australian and South African coal assets to Xstrata.

Mr. Coates is also non-executive director of Santos Limited, and Amalgamated Holdings Ltd. (AHD.AU) and a director at Santos Ltd. (STO.AU), each of which is listed on the Australian Stock Exchange.

Mr. Hayward welcomed the appointment of the new directors, saying they will "prove invaluable in continuing the strength of debate and challenge which has typified the operation of the Company's board since its IPO two years ago."

Write to Alex MacDonald at alex.macdonald@wsj.com

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