LONDON--Newly-minted commodities titan Glencore Xstrata PLC (GLEN.LN) Tuesday sought to reassure investors that its recent $44.6 billion Xstrata purchase will bear fruit through significantly higher-than-expected synergies and reduced capital expenditure.

The Baar, Switzerland-based trader and producer of a wide range of commodities said it now expected to deliver at least $2 billion in synergies in 2014 as a result of the deal, four times as much as it had initially estimated.

The company has identified $450 million in annual synergies to come from marketing activities, $175 million from financing synergies and $1.4 billion through cost savings.

"A significant portion of the synergies are in overhead costs at head and regional offices. We are only just starting to comprehensively look at the combined mining and metallurgical operations," said Chief Executive Ivan Glasenberg.

Glencore finally completed its all-share purchase of Xstrata in May, the largest acquisition in mining history, after a protracted courtship that some analysts said forced Mr. Glasenberg to potentially over-sweeten his terms. Nearly four months after the deal was completed, falling commodity prices and a more conservative reassessment of Xstrata's operations led the company to write down its purchase value by $7.7 billion and report a net loss of $8.92 billion for the first six months of the year.

Mr. Glasenberg said more fat could be cut from the enlarged firm. The company is reducing its capital expenditure by $3.5 billion for the 2013-2015 period.

The company also confirmed that it intends to make an application to the Johannesburg Stock Exchange for a secondary listing, which is expected to become effective during the fourth quarter of 2013, subject to certain approvals.

-Write to Alex MacDonald at alex.macdonald@wsj.com

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