Commodities titan Glencore Xstrata PLC said Thursday it has appointed Tony Hayward, the former BP PLC chief executive, with immediate effect to become its next full-time chairman following a year-long search to replace its previous chairman.

Glencore Xstrata has lacked a full-time chairman since last May, when Mr. Hayward, 56, was appointed interim chairman of the newly minted company. Previous chairman Sir John Bond was ousted following trading house Glencore's $29.5 billion acquisition of mining company Xstrata PLC the same month.

The appointment of a chairman has been closely watched by minority shareholders keen on having a strong board to represent their interests, given the high level of employee ownership at Glencore Xstrata. Chief Executive Ivan Glasenberg has a 8.3% stake, according to the company's annual report, while he and other Glencore employees together own over a third of the company's shares.

Mr. Hayward's appointment completes a remarkable comeback for the former BP boss. BP replaced Mr. Hayward in 2010 following the Deepwater Horizon disaster and subsequent oil spill in the Gulf of Mexico, which cost the company billions of dollars in damages.

Mr. Hayward is also the Chief Executive of oil exploration company Genel Energy PLC, which he co-founded with financier Nathaniel Rothschild.

Write to Alex MacDonald at alex.macdonald@wsj.com

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